Thermodynamical framework for effective mitigation of high aerosol loading in the Indo-Gangetic Plain during winter
Prodip Acharja, Sachin D. Ghude, Baerbel Sinha, M. C. Barth, Gaurav Govardhan, Rachana Kulkarni, Vinayak Sinha, Rajesh Kumar, Kaushar Ali, Ismail Gültepe, Jean‐Eudes Petit, M. Rajeevan
Abstract
Abstract The Indo-Gangetic Plain (IGP) experiences severe air pollution every winter, with ammonium chloride and ammonium nitrate as the major inorganic fractions of fine aerosols. Many past attempts to tackle air pollution in the IGP were inadequate, as they targeted a subset of the primary pollutants in an environment where the majority of the particulate matter burden is secondary in nature. Here, we provide new mechanistic insight into aerosol mitigation by integrating the ISORROPIA-II thermodynamical model with high-resolution simultaneous measurements of precursor gases and aerosols. A mathematical framework is explored to investigate the complex interaction between hydrochloric acid (HCl), nitrogen oxides (NO x ), ammonia (NH 3 ), and aerosol liquid water content (ALWC). Aerosol acidity (pH) and ALWC emerge as governing factors that modulate the gas-to-particle phase partitioning and mass loading of fine aerosols. Six "sensitivity regimes" were defined, where PM 1 and PM 2.5 fall in the "HCl and HNO 3 sensitive regime", emphasizing that HCl and HNO 3 reductions would be the most effective pathway for aerosol mitigation in the IGP, which is ammonia-rich during winter. This study provides evidence that precursor abatement for aerosol mitigation should not be based on their descending mass concentrations but instead on their sensitivity to high aerosol loading.