Photo-induced copper-catalyzed alkynylation and amination of remote unactivated C(sp<sup>3</sup>)-H bonds
Zhusong Cao, Jianye Li, Youwen Sun, Hanwen Zhang, Xueling Mo, Xin Cao, Guozhu Zhang
Abstract
-hydrogen atom transfer. Unactivated secondary and tertiary C-H bonds at β, γ, and δ positions can be functionalized in a predictable manner.
Topics & Concepts
AlkynylationAminationCopperCatalysisChemistryCombinatorial chemistryMedicinal chemistryOrganic chemistryCatalytic C–H Functionalization MethodsSynthesis and Catalytic ReactionsRadical Photochemical Reactions