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Long‐Range Interactions in Diatomic Catalysts Boosting Electrocatalysis

Wenhao Li, Jiarui Yang, Dingsheng Wang

2022Angewandte Chemie44 citationsDOI

Abstract

Abstract The simultaneous presence of two active metal centres in diatomic catalysts (DACs) leads to the occurrence of specific interactions between active sites. Such interactions, referred to as long‐range interactions (LRIs), play an important role in determining the rate and selectivity of a reaction. The optimal combination of metal centres must be determined to achieve the targeted efficiency. To date, various types of DACs have been synthesised and applied in electrochemistry. However, LRIs have not been systematically summarised. Herein, the regulation, mechanism, and electrocatalytic applications of LRIs are comprehensively summarised and discussed. In addition to the basic information above, the challenges, opportunities, and future development of LRIs in DACs are proposed in order to present an overall view and reference for future research.

Topics & Concepts

Diatomic moleculeElectrocatalystBoosting (machine learning)CatalysisNanotechnologySelectivityElectrochemistryChemistryCombinatorial chemistryComputer scienceMaterials scienceMoleculePhysical chemistryArtificial intelligenceElectrodeOrganic chemistryElectrocatalysts for Energy ConversionElectrochemical Analysis and ApplicationsCO2 Reduction Techniques and Catalysts
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