Litcius/Paper detail

Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations

Rui Guo, Xin Zhang, Tong Li, Qian‐Li Li, David A. Ruiz, Liu Leo Liu, Chen‐Ho Tung, Lingbing Kong

2022Chemical Science20 citationsDOIOpen Access PDF

Abstract

An NHC-stabilized aryliminoboryl cation exhibits both boron-centered Lewis acidity and multiple bond reactivity and could be utilized as an effective synthon for unusual cationic boron species.

Topics & Concepts

Cationic polymerizationSynthonBoronReactivity (psychology)ChemistryLewis acids and basesMedicinal chemistryInorganic chemistryPolymer chemistryOrganic chemistryComputational chemistryCatalysisMedicinePathologyAlternative medicineOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compoundsBoron Compounds in Chemistry