Interlayer engineering of V2O5·nH2O by conductive Ni-BTA enabling high-performance aqueous ammonium ion batteries
Zilong Zhang, Yifu Zhang, Zhanming Gao, Tianming Lv, Yanyan Liu, Tao Hu, Changgong Meng
Abstract
Aqueous ammonium ion batteries (AAIBs) are of interest due to the low molar mass , small hydration radius, abundant raw materials and high safety of the carrier ammonium-ion. Nevertheless, there are numerous constraints associated with electrode materials that are suitable for ammonium-ion storage. In this study, we design and synthesize a composite comprising of one-dimensional conductive metal-organic skeleton material (1D c-MOF) embedded between layers of hydrated vanadium pentoxide (VOH) with improved ammonium-ion storage. The central ion of the 1D c-MOF is selected to be the nickel ion , while the ligand is 1,2,4,5-benzenetetramine (BTA). The incorporation of Ni-BTA between the vanadium oxide layers results in the formation of a composite (Ni-BTA/VOH) exhibiting enhanced structural stability , augmented layer spacing and elevated conductivity. Furthermore, the dual energy storage mechanisms of VOH and C N rearrangement act in concert to yield a “1+1 > 2” effect, thereby markedly enhancing the ammonium-ion storage. The specific capacity of Ni-BTA/VOH can reach 183 mAh g −1 at 0.2 A g −1 , and the retention rate can reach 52.5 % after 500 cycles at 2 A g −1 . This work not only proves the potential of Ni-BTA/VOH for widespread application in the field of aqueous batteries , but also provides a new method for structural engineering of VOH with boosted ammonium-ion storage properties.