Facile access to halogenated cationic BC-centered organoborons isoelectronic with alkenyl halides
Libo Xiang, Junyi Wang, Wei Su, Zhenyang Lin, Qing Ye
Abstract
the reaction between carbodiphosphoranes (CDPs) and aryl dihaloboranes is reported. Structural comparison of the halogen and alkoxy derivatives, as well as detailed computational studies, corroborates the polarized double dative bonding nature of the central BC double bonds.
Topics & Concepts
HalideCationic polymerizationChemistryHalogenArylAlkoxy groupDouble bondAryl halideMedicinal chemistryHalogen bondStereochemistryCombinatorial chemistryPolymer chemistryOrganic chemistryAlkylOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compoundsCatalytic Cross-Coupling Reactions