Amplified Spontaneous Emission and Lasing from Zn-Processed AgIn<sub>5</sub>S<sub>8</sub> Core/Shell Quantum Dots
Yang Mi, Anqiang Jiang, Lei Kong, Jun Wang, Heng Guo, Sheng‐Nian Luo
Abstract
I–III–VI ternary quantum dots (QDs) have emerged as favorable alternatives to the toxic II–VI QDs for optoelectronic and biological applications. However, their use as optical gain media for microlasers is still limited by a low fluorescence efficiency. Here, we demonstrate amplified spontaneous emission (ASE) and lasing from colloidal QDs of Zn-processed AgIn 5 S 8 (AIS) for the first time. The passivation treatment on the AIS QDs yields a 3.4-fold enhancement of fluorescence quantum efficiency and a 30% increase in the two-photon absorption cross section. ASE is achieved from the AIS/ZnS core/shell QD films under both one- and two-photon pumping with a threshold fluence of ∼84.5 μJ/cm 2 and 3.1 mJ/cm 2, respectively. These thresholds are comparable to the best optical gain performance of Cd based-QDs reported in the literature. Moreover, we demonstrate a facile whispering-gallery-mode microlaser of the core/shell QDs with a lasing threshold of ∼233 μJ/cm 2 . The passivated AIS QDs can be promising optical gain media for photonic applications.