Reusable, homogeneous water soluble photoredox catalyzed oxidative dehydrogenation of N-heterocycles in a biphasic system: application to the synthesis of biologically active natural products
Santhanam Srinath, R. Abinaya, Arun Prasanth, M. Mariappan, R. Sridhar, Baburaj Baskar
Abstract
Herein, a simple and efficient method for the oxidative dehydrogenation (ODH) of tetrahydro-β-carbolines, indolines and (iso)quinolines is described using a reusable, homogeneous cobalt-phthalocyanine photoredox catalyst in a biphasic medium.
Topics & Concepts
DehydrogenationCatalysisHomogeneousChemistryOxidative phosphorylationCobaltCombinatorial chemistryPhotoredox catalysisOrganic chemistryPhotocatalysisBiochemistryPhysicsThermodynamicsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry ReactionsAsymmetric Hydrogenation and Catalysis