A sustainable strategy for the visible-light-driven facile <i>N</i>-formylation of amines using a Co(<scp>ii</scp>)-embedded covalent organic framework as an efficient photocatalyst
Surya Das, Priyanka Sarkar, Manoj Goswami, Sk. Murshed Ali, Mijanur Rahaman Mollah, Sk. Manirul Islam
Abstract
We have constructed a highly crystalline 2D imine-linked Co( ii )-incorporated Tp-TH COF catalyst (Co( ii )@Tp-TH) with a band gap energy of 2.4 eV to serve as a stable and effective porous photocatalyst for the synthesis of N -formylated amines.
Topics & Concepts
FormylationCovalent bondPhotocatalysisImineCatalysisCovalent organic frameworkVisible spectrumMaterials scienceChemistryPorosityPhotochemistryBand gapCombinatorial chemistryChemical engineeringNanotechnologyOrganic chemistryOptoelectronicsEngineeringCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications