Rh(<scp>iii</scp>)-Catalyzed C–C coupling of unactivated C(sp<sup>3</sup>)–H bonds with iodonium ylides for accessing all-carbon quaternary centers
Pengfei Xie, Huixing Gao, Xingwei Li, Yuqin Jiang, Bingxian Liu
Abstract
Rhodium-catalyzed inert C(sp 3 )–H activation/carbene insertion has been realized, leading to the construction of all-carbon quaternary centers.
Topics & Concepts
ChemistryQuaternary carbonCarbeneRhodiumCatalysisInertCarbon fibersQuaternaryMedicinal chemistryCoupling (piping)Migratory insertionPolymer chemistryStereochemistryOrganic chemistryEnantioselective synthesisEngineeringMechanical engineeringPaleontologyBiologyMaterials scienceComposite numberComposite materialCatalytic C–H Functionalization MethodsCyclopropane Reaction MechanismsSynthesis and Catalytic Reactions