Shedding Light on the Oxidizing Properties of Spin-Flip Excited States in a Cr<sup>III</sup> Polypyridine Complex and Their Use in Photoredox Catalysis
Tobias H. Bürgin, Felix Glaser, Oliver S. Wenger
Abstract
-phenyl pyrrolidine. This work contributes to understanding the fundamental photochemical properties of first-row transition-metal complexes in comparison to well-explored precious-metal-based photocatalysts.
Topics & Concepts
ChemistryExcited statePhotochemistryElectron transferPhotoredox catalysisLigand (biochemistry)Spin statesPhotoinduced electron transferPhotocatalysisCatalysisAtomic physicsInorganic chemistryOrganic chemistryPhysicsBiochemistryReceptorRadical Photochemical ReactionsCO2 Reduction Techniques and CatalystsCatalytic C–H Functionalization Methods