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Preparation of gypsum with high purity and whiteness from phosphogypsum for CO2 mineral sequestration

Man Zhang, Xing Fan

2023Scientific Reports18 citationsDOIOpen Access PDF

Abstract

Abstract Phosphogypsum (PG) is a solid waste product generated during wet-process phosphoric acid production. Various impurities considerably reduce the purity, whiteness, and application range of PG. This article analyzes the physical properties of PG in detail and systematically examines the content and distribution of impurities. Based on the obtained results, a simple process for the efficient removal of almost all impurities in the PG is proposed. The purity and whiteness of the purified gypsum (CaSO 4 ) significantly increased to 99% and 92%, respectively. The migration of impurities and the material balance of this process were then analyzed. Most importantly, the purified gypsum showed high CO 2 sequestration efficiency for CO 2 mineral sequestration, through which a high value-added CaCO 3 product was obtained.

Topics & Concepts

PhosphogypsumGypsumCarbon sequestrationMineralEnvironmental scienceChemistryNatural resource economicsMetallurgyMaterials scienceCarbon dioxideEconomicsRaw materialOrganic chemistryCO2 Sequestration and Geologic InteractionsChemical Looping and Thermochemical ProcessesConcrete and Cement Materials Research
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