Litcius/Paper detail

Lasing from an Organic Micro‐Helix

Chun‐Lin Sun, Jun Li, Qi‐Wei Song, Yu Ma, Zeqi Zhang, Jianbo De, Qing Liao, Hongbing Fu, Jiannian Yao, Hao‐Li Zhang

2020Angewandte Chemie International Edition36 citationsDOIOpen Access PDF

Abstract

Abstract Organic solid‐state semiconductor lasers are attracting ever‐increasing interest for their potential application in future photonic circuits. Despite the great progress made in recent years, an organic laser from 3D chiral structures has not been achieved. Now, the first example of an organic nano‐laser from the micro‐helix structure of an achiral molecule is presented. Highly regular micro‐helixes with left/right‐handed helicity from a distyrylbenzene derivative (HM‐DSB) were fabricated and characterized under microscope spectrometers. These chiral micro‐helixes exhibit unique photonic properties, including helicity‐dependent circularly polarized luminescence (CPL), periodic optical waveguiding, and length‐dependent amplified spontaneous emission (ASE) behavior. The successful observation of laser behavior from the organic micro‐helix extends our understanding to morphology chirality of organic photonic materials and provides a new design strategy towards chiral photonic circuits.

Topics & Concepts

Lasing thresholdPhotonicsChirality (physics)Helix (gastropod)LaserMaterials scienceHelicityOptoelectronicsLuminescenceOrganic semiconductorNanotechnologyOpticsPhysicsWavelengthChiral symmetryQuarkBiologyParticle physicsSnailNambu–Jona-Lasinio modelEcologyQuantum mechanicsLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic CompoundsPorphyrin and Phthalocyanine Chemistry