Mixed mechanisms of bond exchange in covalent adaptable networks: monitoring the contribution of reversible exchange and reversible addition in thiol–succinic anhydride dynamic networks
Maciej Podgórski, Nathan Spurgin, Sudheendran Mavila, Christopher N. Bowman
Abstract
Thioester anhydride reversible addition and thiol–thioester reversible exchange are discussed as two competing mechanisms dictating the dynamic response in thiol–succinic anhydride dynamic networks.
Topics & Concepts
Succinic anhydrideThioesterThiolCovalent bondDynamic covalent chemistryChemistryPhotochemistryPolymer chemistryOrganic chemistryMoleculeEnzymeSupramolecular chemistryPolymer composites and self-healingAxial and Atropisomeric Chirality SynthesisSynthesis of Indole Derivatives