On the absolute photoionization cross section and threshold photoelectron spectrum of two reactive ketenes in lignin valorization: fulvenone and 2-carbonyl cyclohexadienone
Zeyou Pan, András Bödi, Jeroen A. van Bokhoven, Patrick Hemberger
Abstract
as a calibrant. The PICS of 2-carbonyl cyclohexadienone was found to be 21.5 ± 8.6 Mb at 9 eV. Our PICS measument will enable the quantification of reactive ketenes in lignin valorization and combustion processes using photoionization techniques and provide advanced mechanistic and kinetics insights to aid the bottom-up optimization of such processes.
Topics & Concepts
PhotoionizationChemistryLigninSection (typography)Cross section (physics)Absolute (philosophy)PhotochemistryComputational chemistryOrganic chemistryIonizationPhysicsComputer scienceQuantum mechanicsEpistemologyIonOperating systemPhilosophyLignin and Wood ChemistryPlant Gene Expression AnalysisEnzyme-mediated dye degradation