Regiodivergent sulfonylarylation of 1,3-enynes <i>via</i> nickel/photoredox dual catalysis
Ya Chen, Kun Zhu, Qingqin Huang, Yixin Lü
Abstract
)-1,3-dienyl sulfones with high chemo-, regio- and stereoselectivity through 3,4-sulfonylarylation. Notably, this is the first example that nickel and photoredox catalysis are merged to achieve efficient and versatile difunctionalization of 1,3-enynes.
Topics & Concepts
CatalysisStereoselectivityChemistryCombinatorial chemistryNickelConjugated systemSelectivityDual (grammatical number)Organic chemistryArtPolymerLiteratureSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions