Litcius/Paper detail

Communication—Functional Conductive Polymer Binder for Practical Si-Based Electrodes

Tianyu Zhu, Gao Liu

2021Journal of The Electrochemical Society23 citationsDOIOpen Access PDF

Abstract

Multifunctional conductive binders represent an emerging class of polymer materials to address inherent challenges of Si electrodes for high capacity lithium-ion batteries. Advanced binders with oriented functionalities are greatly desired to facilitate the battery chemistry. We here report stable capacity cycling of a practical composite anode comprising industrial available SiO x (>60 wt%), carbon materials and a conductive polymer binder—poly(9,9-dioctylfluorene- co -fluorenonecomethylbenzoic ester) (PFM). This multifunctional polymer functions as both an interface modifier and an electrode binder for high-performing SiO x composite electrodes. The viability of multifunctional conductive polymer binders was further validated in a practical full cell.

Topics & Concepts

Materials scienceAnodeElectrical conductorElectrodePolymerConductive polymerBattery (electricity)Composite numberLithium (medication)Lithium batteryNanotechnologyComposite materialIonChemistryIonic bondingOrganic chemistryMedicinePhysical chemistryQuantum mechanicsPhysicsPower (physics)EndocrinologyAdvancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications