Post-synthetic modulation of UiO-66-NH<sub>2</sub> with a cobaloxime catalyst for efficient hydrogen production
Saddam Sk, Sandip Prabhakar Shelake, Dependu Dolui, Suhana Karim, Rajib Ghosh, M. V. Jyothirmai, Annadanam V. Sesha Sainath, Ujjwal Pal, Arnab Dutta
Abstract
Post synthetically-modified UiO-66-NH 2 with a molecular cobaloxime [Co(DMG) 2 Cl 2 ] (DMG = dimethylglyoxime) catalyst displays excellent photo-(404 μmol g −1 h −1 ) and electrocatalytic H 2 evolution activity in an aqueous solution.
Topics & Concepts
DimethylglyoximeCatalysisHydrogen productionAqueous solutionChemistryHydrogenNuclear chemistryInorganic chemistryOrganic chemistryCobaltAdvanced Photocatalysis TechniquesMetalloenzymes and iron-sulfur proteinsMetal-Organic Frameworks: Synthesis and Applications