Mechanochemical Synthesis and Structure of Lithium Tetrahaloaluminates, LiAlX<sub>4</sub> (X = Cl, Br, I): A Family of Li-Ion Conducting Ternary Halides
Nicolás Flores-González, Nicolò Minafra, Georg F. Dewald, Hazel Reardon, Ronald I. Smith, Stefan Adams, Wolfgang G. Zeier, Duncan H. Gregory
Abstract
at 333 K, coupled with the highest thermal and oxidative stability. Modeling of the diffusion pathways suggests that the Li-ion transport mechanism in each tetrahaloaluminate is closely related and mediated by both halide polarizability and concerted complex anion motions.
Topics & Concepts
HalideLithium (medication)ElectrochemistryMonoclinic crystal systemTernary operationIonic conductivityChemistryThermal stabilityIonConductivityIodideInorganic chemistryPolarizabilityElectrolyteIonic bondingCrystallographyMaterials sciencePhysical chemistryCrystal structureOrganic chemistryMoleculeElectrodeMedicineEndocrinologyComputer scienceProgramming languageAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic ConductivityAdvancements in Battery Materials