Four-Electron Redox Reaction in Prussian Blue Analogue Cathode Material for High-Performance Sodium-Ion Batteries
Xiaoying Zhao, Ningbo Liu, Mengxian Zheng, Xiaohan Wang, Yinuo Xu, Jingwei Liu, Fujun Li, Liubin Wang
Abstract
Prussian blue analogues (PBAs) are considered promising cathode materials for sodium-ion batteries (SIBs). However, traditional PBAs have limitations, such as up to two-electron-transfer reactions, lattice vacancies, coordinated water, and poor intrinsic conductivity, leading to low capacity and poor rate performance. Herein, we have developed vacancy/water-free silver hexacyanoferrate nanoparticles interlinked with carbon nanotubes (AgHCF@CNTs) to improve the electrochemical performance. Benefiting from the four-electron redox capacity of Fe 3+ /Fe 2+ and Ag + /Ag, the AgHCF@CNTs exhibit a reversible capacity of 168.4 mAh g –1 at 50 mA g –1, high rate capability (90.7 mAh g –1 at 2 A g –1 ), and long cycling stability over 500 cycles. The in-situ-generated Ag during the discharging/charging process, along with the large interstitial spaces of ferricyano-coordination groups, facilitate electron transfer and Na + transportation, guaranteeing high electrochemical performance. This study provides insights into the design and synthesis strategy for advancing multiple-electron redox hexacyanoferrate as cathode materials for high-performance SIBs.