The role of phonons in switchable MOFs: a model material perspective
Alexander E. J. Hoffman, Irena Senkovska, Leila Abylgazina, Volodymyr Bon, Veronika Grzimek, Anna Maria Dominic, Margarita Russina, Marvin A. Kraft, Inez M. Weidinger, Wolfgang G. Zeier, Véronique Van Speybroeck, Stefan Kaskel
Abstract
The role of phonons in switchable DUT-8(M) MOFs involving Ni, Co, Zn, or Cu as metal (M) was studied by Raman spectroscopy, inelastic neutron scattering (INS), and phonon acoustic spectroscopy (PAS) and density functional theory (DFT) calculations.
Topics & Concepts
PhononRaman spectroscopyInelastic neutron scatteringDensity functional theoryMaterials scienceNeutron spectroscopySpectroscopyCondensed matter physicsRaman scatteringInelastic scatteringNeutronNeutron scatteringCrystallographyScatteringChemistryComputational chemistryPhysicsOpticsQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Fluorides and Related CompoundsMagnesium Oxide Properties and Applications