Transforming Waste Biomass into N-Rich Carbon Dots with Built-In Active Sites for Efficient CO<sub>2</sub> Photoreduction from Flue Gas
Ganghua Zhou, Chuanzhou Bi, Xin Qian, Yanglin Chen, Hailong Liu, Xin Ning, Can Xue, Penghui Ding, Xiaozhi Wang, Xingwang Zhu
Abstract
The direct conversion of CO 2 from simulated flue gas to chemical feedstock gases using solar energy remains a significant challenge. A fundamental difficulty is the design of catalyst surfaces with high CO 2 affinity and the improvement of photocatalytic accumulation efficiency. Herein, we developed a facile synthesis strategy to prepare model anatase photocatalyst (Ti-EBCD) surface-functionalized with waste-biomass-derived carbon dot (EBCD) for CO 2 conversion. Importantly, the abundant functional groups and intrinsically active pyridinic-N sites in Ti-EBCD construct a CO 2 -affinitive surface, thereby enhancing the CO 2 adsorption and activation. The optimized Ti-EBCD catalyst not only achieves a tunable syngas conversion with pure CO 2 but also exhibits high CO selectivity during simulated flue gas conversion. A series of characterizations, in situ experiments, and theoretical calculations were employed to establish structure–activity relationships and reveal the reaction mechanisms behind the enhanced selective conversion of simulated flue gas. We anticipate that this work will provide insights into the development of advanced surface-engineered photocatalysts for solar-driven simulated flue gas conversion.