On the supramolecular properties of neutral, anionic and cationic cadmium complexes harvested from dithiolate–polyamine binary ligand systems
Suman Adhikari, Tirtha Bhattacharjee, Arijit Das, Subhadip Roy, Constantin G. Daniliuc, Jan K. Zaręba, Antonio Bauzá, Antonio Frontera
Abstract
Three Cd(<sc>ii</sc>) complexes [Cd(i-mnt)(DMSO)<sub>2</sub>]<sub>n</sub> (<bold>1</bold>), {[Cd(i-mnt)pn]·2H<sub>2</sub>O} (<bold>2</bold>), and [Cd(i-mnt)<sub>3</sub>][Cd(tren)<sub>2</sub>]<sub>2</sub> (<bold>3</bold>) harvested from 1,1-dicyanoethylene-2,2-dithiolate (i-mnt<sup>2−</sup>) and polyamine ligand systems have been designed, synthesized and structurally characterized.
Topics & Concepts
PolyamineChemistryCationic polymerizationLigand (biochemistry)CrystallographySupramolecular chemistryCadmiumStereochemistryCrystal structurePolymer chemistryReceptorBiochemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchMagnetism in coordination complexes