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Y3+ and Sm3+ co-doped mixed metal oxide nanocomposite: Structural, electrochemical, photocatalytic, and antibacterial properties

Karthik Kannan, Devi Radhika, D. Gnanasangeetha, L. Sivarama Krishna, K. Gurushankar

2021Applied Surface Science Advances69 citationsDOIOpen Access PDF

Abstract

Nanocomposite materials (rare-earth doped) are famous and tend to demonstrate good features in all the fields like photocatalysis, electrochemical, and antibacterial. A Wet-chemical route was used to prepare NiO-CYO-CSO [NiO-Ce0.9Y0.1O2-δ–Ce0.9Sm0.1O2-δ] nanocomposite successfully for different uses. The growth of fluorite cubic structure and absence of secondary phase was detected by X-ray diffraction. Metal-oxygen bond at 410.7 cm−1 was unveiled by Fourier transform infrared spectroscopy. The morphology and element composition of the material was characterized using Scanning electron microscopy and Energy dispersive absorption X-ray spectroscopy. The optical bandgap of the sample was deliberated using UV-Vis spectroscopy and the projected bandgap of NiO-CYO-CSO composite was found to be 3.54 eV. Impedance studies were done at conditions such as the frequency range (40 to 6 kHz) and voltage-1.3 V. The photocatalytic and antibacterial activities of NiO-CYO-CSO nanocomposite was also examined. Furthermore, the synthesized NiO-CYO-CSO will apply to wastewater treatment and pharmaceutical applications.

Topics & Concepts

Non-blocking I/OMaterials scienceNanocompositePhotocatalysisFourier transform infrared spectroscopyDielectric spectroscopyOxideBand gapChemical engineeringScanning electron microscopeDopingNuclear chemistryElectrochemistryAnalytical Chemistry (journal)NanotechnologyComposite materialMetallurgyElectrodeChemistryOptoelectronicsOrganic chemistryPhysical chemistryCatalysisEngineeringElectronic and Structural Properties of OxidesAdvancements in Solid Oxide Fuel CellsLuminescence Properties of Advanced Materials