Hyperpolarisation of weakly binding N-heterocycles using signal amplification by reversible exchange
Peter J. Rayner, Joseph P. Gillions, Valentin D. Hannibal, Richard O. John, Simon B. Duckett
Abstract
(NHC)(sulfoxide)(sub)] where X = Cl, Br or I. These complexes are shown to undergo very rapid ligand exchange and lower temperatures dramatically improve the efficiency of these SABRE catalysts.
Topics & Concepts
ChemistrySIGNAL (programming language)Computer scienceCombinatorial chemistryProgramming languageAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyElectron Spin Resonance Studies