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Review—Corrosion-Resistant Metastable Al Alloys: An Overview of Corrosion Mechanisms

J. Esquivel, Rajeev Gupta

2020Journal of The Electrochemical Society63 citationsDOIOpen Access PDF

Abstract

Commercial aluminum alloys exhibit localized corrosion when exposed to environments containing aggressive anions. Alloying of Al with specific elements (M: Cr, Mo, V, Nb, etc) using non-equilibrium processing techniques has been reported to result in significantly improved corrosion resistance due to the formation of a supersaturated solid solution and uniform distribution of M in the matrix. Several theories describing the corrosion behavior of Al–M alloys have been postulated. This paper presents an overview of the most common non-equilibrium alloying techniques implemented for the production of the metastable Al–M alloys and posited corrosion mechanisms for the improved corrosion resistance.

Topics & Concepts

CorrosionMetastabilityMaterials scienceMetallurgySupersaturationAluminiumThermodynamicsChemistryPhysicsOrganic chemistryCorrosion Behavior and InhibitionAluminum Alloy Microstructure PropertiesHigh-Temperature Coating Behaviors
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