Activating graphite with defects and oxygenic functional groups to boost sodium-ion storage
Juanxia Ding, Xiaozhong Zhou, Jian Gao, Ziqiang Lei
Abstract
even after 4500 cycles for the AG-50 electrode with the 50-hour ball-milling treatment, amounting to a very low decay ratio of 0.0034% per cycle. Based on physical characterizations and density functional theory calculations, the greatly improved specific capacity and cycling stability of the AG anode for sodium-ion storage can be attributed to the enlarged interlayer space, increased specific surface area, and introduced defects caused by ball-milling treatment, which provide vast active sites for reversible sodium-ion storage based on a adsorption/desorption mechanism, thus leading to great improvement in the specific capacity of the AG electrode. These results can provide a meaningful reference for the application of modified graphite for high-performance sodium storage.