A highly conducting tetrathiafulvalene-tetracarboxylate based dysprosium(<scp>iii</scp>) 2D metal–organic framework with single molecule magnet behaviour
Fabio Manna, Mariangela Oggianu, Pascale Auban-Senzier, Ghénadie Novitchi, Enric Cañadell, Maria Laura Mercuri, Narcis Avarvari
Abstract
By self-assembling the redox-active TTF-tetracarboxylate linker with the Dy III ion, a 2D MOF, showing a rare topology and coexistence of a record conductivity and SMM behavior, has been obtained.
Topics & Concepts
DysprosiumTetrathiafulvaleneLinkerMetalMetal-organic frameworkMoleculeConductivityRedoxMagnetIonSingle-molecule magnetMaterials scienceInorganic chemistryChemistryTopology (electrical circuits)Chemical physicsPhysical chemistryOrganic chemistryPhysicsComputer scienceMagnetic fieldMagnetizationQuantum mechanicsOperating systemAdsorptionCombinatoricsMathematicsMagnetism in coordination complexesOrganic and Molecular Conductors ResearchMetal-Organic Frameworks: Synthesis and Applications