Vibrational CD study on the solution phase structures of the MacMillan catalyst and its corresponding iminium ion
Tino P. Golub, Christian Merten
Abstract
, we report a comprehensive analysis of the conformational preferences in two solvents. VCD spectroscopy is subsequently shown to be able to reveal small conformational changes induced by solute-solvent and solute-anion interactions.
Topics & Concepts
IminiumCatalysisIonPhase (matter)ChemistryOrganic chemistryMolecular spectroscopy and chiralityAnalytical Chemistry and ChromatographySurface Chemistry and Catalysis