Supramolecular multi-electron redox photosensitisers comprising a ring-shaped Re(<scp>i</scp>) tetranuclear complex and a polyoxometalate
Maria Takahashi, Tsuyoshi Asatani, Tatsuki Morimoto, Yoshinobu Kamakura, Kotaro Fujii, Masatomo Yashima, Naoki Hosokawa, Yusuke Tamaki, Osamu Ishitani
Abstract
Supramolecular photosensitisers comprising a ring-shaped Re( i ) tetranuclear complex and a Keggin-type heteropolyoxometalate were synthesised. They can photochemically accumulate four electrons and supply them for the photocatalytic CO 2 reduction.
Topics & Concepts
PolyoxometalateRedoxRing (chemistry)Supramolecular chemistryChemistryElectronCrystallographyStereochemistryCombinatorial chemistryInorganic chemistryOrganic chemistryCatalysisPhysicsCrystal structureQuantum mechanicsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in CatalysisMetal-Organic Frameworks: Synthesis and Applications