New bis[<i>cis</i>-{MoO<sub>2</sub>}] complexes with dihydrazone ligands: synthesis, characterization, theoretical investigation and their peroxidase mimicking activity
Lata Rana, Dheeraj, Geeta Hundal
Abstract
Three dihydrazone-derived binuclear dioxidomolybdenum complexes are synthesised, and their peroxidase mimicking activities with pyrogallol and dopamine are reported using H 2 O 2 as an oxidant.
Topics & Concepts
PyrogallolChemistryMolybdenumOctahedronProton NMRCrystallographyElemental analysisOctahedral molecular geometryAtom (system on chip)Single crystalCrystal structureInorganic chemistryStereochemistryOrganic chemistryEmbedded systemComputer scienceMetal complexes synthesis and propertiesVanadium and Halogenation ChemistryMetal-Catalyzed Oxygenation Mechanisms