Electrochemical Oxidative Dehydrogenative Coupling of Sulfoximines to Construct N‐sulfenyl and N‐phosphinyl Sulfoximines
Xiaoman Li, Jiawei Huang, Liang Xu, Jichang Liu, Yu Wei
Abstract
Abstract Herein, an electrochemical oxidative approach for the synthesis of N‐sulfenyl and N‐phosphinyl sulfoximines has been established from readily available NH‐sulfoximines with thiophenols and diarylphosphine oxides. Utilizing the synergistic effect of halide salt and electrochemical oxidation, the desired products are obtained at room temperature in the absence of any acidic/basic/metallic additives.
Topics & Concepts
ChemistryElectrochemistryHalideOxidative phosphorylationCoupling (piping)Salt (chemistry)Combinatorial chemistryOrganic chemistryElectrodeMetallurgyPhysical chemistryBiochemistryMaterials scienceSynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques