Tuning Phase Transition and Thermochromic Properties of Vanadium Dioxide Thin Films via Cobalt Doping
Xun Geng, Tianci Chang, Jiaxin Fan, Yu Wang, Xiaotian Wang, Yunlong Sun, S. Premkumar, Chuang Liu, Chun‐Ho Lin, Xiaolin Wang, Jack Yang, Zhenxiang Cheng, Kourosh Kalantar‐Zadeh, Xun Cao, Danyang Wang, Ajayan Vinu, Jiabao Yi, Tom Wu
Abstract
Vanadium dioxide (VO2) featuring a distinct thermally triggered phase transition is regarded as the most attractive thermochromic material for smart window applications. However, the high transition temperature (∼67 °C) and moderate luminous transmittance (<50%) of the pristine VO2 circumvent room temperature applications. In this work, epitaxial cobalt-doped VO2 thin films were fabricated to tailor the electric and optical properties on a c-plane sapphire substrate. At the highest doping concentration of 10%, the transition temperature of VO2 is reduced to 44 °C, accompanied by a high luminous transmittance of 79% for single-element Co-doped VO2. The roles of cobalt doping and detailed band variation are fully explained experimentally and by modeling (DFT calculation), respectively. Furthermore, the dramatically increased carrier concentration in cobalt-doped VO2 underscores the promising future of cobalt-doped VO2 unveiled by temperature-dependent Hall effect measurement.