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Strategies for Design of Potential Singlet Fission Chromophores Utilizing a Combination of Ground-State and Excited-State Aromaticity Rules

Ouissam El Bakouri, Joshua R. Smith, Henrik Ottosson

2020Journal of the American Chemical Society139 citationsDOIOpen Access PDF

Abstract

+ 2 rules, together with substituent effects (electronic and steric) and benzannelation, can be used to tailor new chromophores with potential use in singlet fission photovoltaics.

Topics & Concepts

ChemistrySinglet fissionChromophoreExcited stateAromaticitySinglet stateGround stateState (computer science)FissionPhotochemistryComputational chemistryAtomic physicsMoleculeOrganic chemistryNuclear physicsNeutronComputer scienceAlgorithmPhysicsSynthesis and Properties of Aromatic CompoundsFullerene Chemistry and ApplicationsLuminescence and Fluorescent Materials