A thiolated copper-hydride nanocluster with chloride bridging as a catalyst for carbonylative C–N coupling of aryl amines under mild conditions: a combined experimental and theoretical study
Anish Kumar Das, Sourav Biswas, Amit Pal, Surya Sekhar Manna, Avirup Sardar, Pradip Kumar Mondal, Basudev Sahoo, Biswarup Pathak, Sukhendu Mandal
Abstract
A Cu( i ) nanocluster, with its precisely defined core and shell components, plays a pivotal role in mediating carbonylative C–N coupling reactions.
Topics & Concepts
CatalysisChemistryArylNanoclustersRadicalAnilineCopperCatalytic cyclePhotochemistryCombinatorial chemistryOrganic chemistryAlkylNanocluster Synthesis and ApplicationsCarbon and Quantum Dots ApplicationsQuantum Dots Synthesis And Properties