Photosalient effect and reversible photochromic photoluminescence driven by cascade [2 + 2] cycloaddition reaction and water adsorption in a 0D hybrid metal halide
Chudong Chen, Ziquan Li, Yonghong Xiao, Chenghao Ye, Jianwu Wei, Ruosheng Zeng, Qi Pang, Binbin Luo
Abstract
. At last, by integrating powdered 1 with polymethyl methacrylate (PMMA), the 1-PMMA hybrid matrix membrane exhibited rapid and controllable responsive behaviors, including bending and curling, through controlling the direction of the concentration gradient. This work demonstrates that ionic HMHs might function as a promising platform for advanced photomechanical and photochromic materials.
Topics & Concepts
PhotochromismHalidePhotoluminescenceCycloadditionAdsorptionCascadePhotochemistryMetalChemistryInorganic chemistryMaterials scienceOrganic chemistryCatalysisOptoelectronicsChromatographyPhotochromic and Fluorescence ChemistryPolyoxometalates: Synthesis and ApplicationsRadical Photochemical Reactions