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A strategy of chiral cation coordination to achieve a large luminescence dissymmetry factor in 1D hybrid manganese halides

Fei Wang, Xingjun Li, Tianqi Chen, Liqing Wang, Chenliang Li, Wei Zhang, Wen Yuan, Shan Lu, Lina Li, Xueyuan Chen

2025Chemical Science13 citationsDOIOpen Access PDF

Abstract

A pair of Mn-based bromide enantiomers R / S -DACAMnBr 3 were synthesized via a strategy of chiral cation coordination, which exhibited a large g lum up to 0.292, positive magneto-chiroptical effect, and great optoelectronic application potential.

Topics & Concepts

ManganeseHalideLuminescenceChemistryCoordination complexCombinatorial chemistryInorganic chemistryMaterials scienceOptoelectronicsOrganic chemistryMetalLanthanide and Transition Metal ComplexesPerovskite Materials and ApplicationsAdvanced Condensed Matter Physics