Novel stable ytterbium acetylacetonate–quinaldinate complexes as single-molecule magnets and surprisingly efficient luminophores
Andrey V. Gavrikov, Andrey B. Ilyukhin, Ilya V. Taydakov, Mikhail T. Metlin, N. P. Datskevich, Mikhail E. Buzoverov, Konstantin A. Babeshkin, Nikolay N. Efimov
Abstract
Novel heteroleptic Yb quinoline-2-carboxylate complexes exhibiting properties of field-induced single-molecule magnets (SMMs) and near IR luminophores are reported. Despite a lot of C–H quenchers, high photoluminescence quantum yield can be achieved.
Topics & Concepts
Ligand (biochemistry)ChemistryPhotoluminescenceCrystallographyMoleculeCoordination sphereOctahedronLanthanideQuinolineCarboxylateStereochemistryIonMaterials scienceCrystal structureOrganic chemistryBiochemistryReceptorOptoelectronicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry