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Tunable third-order nonlinear optical effect <i>via</i> modifying Ti<sub>4</sub>(embonate)<sub>6</sub> cage-based ionic pairs

Guang‐Hui Chen, Yan‐Ping He, Zirui Wang, Qiaohong Li, Zhi‐Zhou Ma, Jian Zhang

2022Inorganic Chemistry Frontiers15 citationsDOI

Abstract

The integration of Ti 4 L 6 (L = embonate) cages and various N , N -chelated transition-metal cations into tightly packed structures accurately leads to high-performance materials with adjustable nonlinear optical (NLO) effects.

Topics & Concepts

Nonlinear opticalCageIonic bondingNonlinear systemTransition metalMaterials scienceOrder (exchange)MetalNonlinear opticsCrystallographyPhysical chemistryChemistryChemical physicsIonPhysicsMathematicsCatalysisOrganic chemistryCombinatoricsMetallurgyQuantum mechanicsFinanceEconomicsPorphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchNonlinear Optical Materials Studies
Tunable third-order nonlinear optical effect <i>via</i> modifying Ti<sub>4</sub>(embonate)<sub>6</sub> cage-based ionic pairs | Litcius