Pseudo-mono-axial ligand fields that support high energy barriers in triangular dodecahedral Dy(<scp>iii</scp>) single-ion magnets
Ben Zhang, Zhijie Cheng, Yingying Wu, Lei Chen, Rong Jing, Xingwei Cai, Chunhui Jiang, Yi‐Quan Zhang, Aihua Yuan, Hui−Hui Cui, Zhao‐Yang Li
Abstract
calculations were used to show the apparent difference in the magnetic dynamics of the three complexes, confirming that the pseudo-mono-axial ligand field has an important effect on high-performance SMMs compared with the local symmetry. This study not only presents the highest energy barrier for a triangular dodecahedral SMM but also highlights the enormous potential of the pseudolinear Dy-L ligand field for constructing promising SMMs.
Topics & Concepts
DodecahedronMagnetIonLigand (biochemistry)LanthanideMaterials scienceCrystallographyChemistryEngineeringMechanical engineeringReceptorOrganic chemistryBiochemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications