Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex
Laurence R. Doyle, Martin R. Galpin, Samantha K. Furfari, Bengt E. Tegner, Antonio J. Martı́nez-Martı́nez, Adrian C. Whitwood, Scott A. Hicks, Guy C. Lloyd‐Jones, Stuart A. Macgregor, Andrew S. Weller
Abstract
, as promoted by the solid-state microenvironment.
Topics & Concepts
ChemistryCyclooctaneAlkaneRhodiumSingle crystal1,5-CyclooctadieneQuenching (fluorescence)Crystal (programming language)CrystallographyReactivity (psychology)Density functional theoryPhysical chemistryComputational chemistryOrganic chemistryHydrocarbonCatalysisAlternative medicineFluorescenceProgramming languagePathologyPhysicsMedicineComputer scienceQuantum mechanicsOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and CatalysisAdvanced NMR Techniques and Applications