From <i>Operando</i> Raman Mechanochemistry to “NMR Crystallography”: Understanding the Structures and Interconversion of Zn-Terephthalate Networks Using Selective <sup>17</sup> O-Labeling
César Leroy, Thomas‐Xavier Métro, Ivan Hung, Zhehong Gan, Christel Gervais, Danielle Laurencin
Abstract
Raman spectroscopy studies, which would not have been possible with hydrogenated equivalents. Overall, the synthetic and spectroscopic approaches developed herein are expected to push forward the understanding of the structure and reactivity of other complex coordination networks and MOFs.
Topics & Concepts
MechanochemistryRaman spectroscopyNuclear magnetic resonance spectroscopyBall millDensity functional theorySpectroscopyIsotopic labelingChemistryCrystallographyCarboxylateMaterials scienceComputational chemistryStereochemistryOrganic chemistryOpticsPhysicsComposite materialQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced NMR Techniques and ApplicationsMagnetism in coordination complexes