Visible-light driven photocatalytic CO<sub>2</sub>reduction promoted by organic photosensitizers and a Mn(<scp>i</scp>) catalyst
Elena Bassan, Rei Inoue, David C. Fabry, Francesco Calogero, Simone Potenti, Andrea Gualandi, Pier Giorgio Cozzi, Kei Kamogawa, Paola Ceroni, Yusuke Tamaki, Osamu Ishitani
Abstract
Organic chromophores displaying TADF emission were coupled to a Mn( i )-complex as the catalyst and investigated as photosensitizers for CO 2 reduction. Upon 470 nm LED excitation, TON CO+HCOOH > 650 and a Φ CO+HCOOH = 22.8% were obtained.
Topics & Concepts
CatalysisPhotocatalysisChromophorePhotochemistryVisible spectrumChemistryMaterials scienceOptoelectronicsOrganic chemistryCO2 Reduction Techniques and CatalystsLuminescence and Fluorescent MaterialsOrganic Light-Emitting Diodes Research