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Dehydrogenation of iron amido-borane and resaturation of the imino-borane complex

Xiaofang Zhai, Maofu Pang, Lei Feng, Jiong Jia, Chen‐Ho Tung, Wenguang Wang

2021Chemical Science14 citationsDOIOpen Access PDF

Abstract

Dehydrogenation of an amido-borane iron complex provides an imino-borane complex. Regeneration of the amido-borane precursor was achieved by protonation of the imino-borane followed by hydride transfer to the amino-borane intermediate.

Topics & Concepts

BoraneDehydrogenationChemistryProtonationHydrideAmmonia boraneOrganic chemistryCatalysisHydrogenIonHydrogen Storage and MaterialsOrganoboron and organosilicon chemistryAmmonia Synthesis and Nitrogen Reduction
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