Effect of the cross-linker length of thiophene units on photocatalytic hydrogen production of triazine-based conjugated microporous polymers
Xiao Han, Yan Zhang, Yunyun Dong, Jinsheng Zhao, Shouli Ming, Junhong Zhang
Abstract
). Also, BTPT-CMP1 possesses a higher hydrogen evolution rate than most reported 1,3,5-triazine based conjugated polymers. These results demonstrate that the cross-linker length has great influence on the photocatalytic properties of conjugated microporous polymers, which offers theoretical direction for designing high-performance CMPs.
Topics & Concepts
Conjugated microporous polymerMicroporous materialConjugated systemPolymerTriazineLinkerThermal stabilityMaterials sciencePhotocatalysisThiopheneChemical engineeringHydrogen productionHydrogenPhotochemistryPolymer chemistryChemistryOrganic chemistryCatalysisComposite materialComputer scienceOperating systemEngineeringCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications