Hydrothermally synthesized nitrogen-doped hydrochar from sawdust biomass for supercapacitor electrodes

Abstract

Porous carbon generated from biomass is among the most promising electrode materials for supercapacitor applications. In this research work, sawdust was used as a carbon source to synthesize N-doped hydrochars via the hydrothermal method in the presence of nitrogen-containing compounds including ammonium chloride, urea agar, ammonium molybdate tetrahydrate, and mammalian urine, followed by chemical activation by potassium hydroxide. Using the hydrothermal technique, it was possible to dope 7.06 wt% of nitrogen into the hydrochar. The as synthesized materials were characterized by TGA/DTA, FTIR, BET, XRD, SEM/EDS, XPS, and proximate analysis. Furthermore, EIS, CV, and GCD were used to assess electrochemical performance. All the N-doped hydrochars synthesized samples possess crystalline and mesoporous structures with hydroxyl and amide functional groups. The KOH activation improved the specific surface area and pore volume by 8.5% and 21%, respectively. The maximum specific surface area and pore volume were found to be 560.72 m 2 /g and 0.2246 cc/g, respectively. The CV findings demonstrate the battery-like characteristics of the electrocatalysts made with molybdenum (VI) oxide (MoO 3 ) embedded in these N-doped hydrochars, yielding 35.16 F/g specific capacitance at 10 mV/s. In contrast, the GCD's specific capacitance displays 80 F/g at 0.5 Ag -1 . • Nitrogen was successfully doped on the hydrochars derived from sawdust, using tandem hydrothermal carbonization in the presence of various nitrogen precursors. • N-doped hydrochars were characterized in detail using advanced characterization techniques by TGA, FTIR, XRD, BET, SEM/EDS, XPS, CV, EIS, GCD. • The synthesized materials possess battery-like properties, providing 80 F/g specific capacitance at 0.5 Ag -1 .

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