The Pink Box: Exclusive Homochiral Aromatic Stacking in a Bis-perylene Diimide Macrocycle
Samuel E. Penty, Martijn A. Zwijnenburg, Georgia R. F. Orton, Patrycja Stachelek, Róbert Pál, Yujie Xie, Sarah L. Griffin, Timothy A. Barendt
Abstract
at 675 nm). Finally, excellent through-space PDI-PDI π-orbital overlap stabilizes PDI reduced states, akin to covalent functionalization with electron-withdrawing groups.
Topics & Concepts
ChemistryDiimidePeryleneStackingPolymer chemistryCrystallographyStereochemistryOrganic chemistryMoleculeSynthesis and Properties of Aromatic CompoundsMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials