Strategic molecular design of <i>closo-ortho</i>-carboranyl luminophores to manifest thermally activated delayed fluorescence
Dong Kyun You, Hyunhee So, Chan Hee Ryu, Mingi Kim, Kang Mun Lee
Abstract
-carborane-appended π-conjugated (D-A) system, which forms a rigid geometry due to severe intramolecular steric hindrance, can enhance the radiative efficiency for ICT-based emission and trigger the TADF nature.
Topics & Concepts
FluorescencePhotochemistryChemistryPhysicsQuantum mechanicsBoron Compounds in ChemistryLuminescence and Fluorescent MaterialsSupramolecular Chemistry and Complexes