Effectiveness of the preparation of maleic anhydride grafted poly (lactic acid) by reactive processing for poly (lactic acid)/carbon nanotubes nanocomposites
Gleice Ellen Almeida Verginio, Thaís Larissa do Amaral Montanheiro, Larissa Stieven Montagna, Juliano Marini, Fábio Roberto Passador
Abstract
Abstract An effective strategy to increase the properties of poly (lactic acid) (PLA) is the addition of carbon nanotubes (CNT). In this work, aiming to improve the surface adhesion of PLA and CNT a new compatibilizer agent was prepared by reactive processing, PLA grafted maleic anhydride (PLA‐ g ‐MA) using benzoyl peroxide and maleic anhydride. The effectiveness of the PLA‐ g ‐MA as a compatibilizer agent was verified for PLA/PLA‐ g ‐MA/CNT nanocomposites. PLA and PLA‐ g ‐MA samples were characterized by Fourier transform infrared spectroscopy (FT‐IR) to confirm the grafting reaction of maleic anhydride on PLA chains and by rheological analysis to prove the changes in the matrix PLA after the graphitization reaction. Thermal (differential scanning calorimetry and thermogravimetric analysis), mechanical tests (Izod impact strength and tensile test), and morphological characterization were used to verify the effect of the compatibilizer agent. The preparation of PLA‐ g ‐MA by reactive extrusion processing proved satisfactory and the nanocomposites presented good thermal and mechanical properties. The addition of the PLA‐ g ‐MA also contributed to the greater distribution of CNT and can be used as an alternative for the production of PLA/CNT nanocomposites.