Litcius/Paper detail

Photocarboxylation of remote C–H bonds through nitrogen-centred radical 1,5-hydrogen atom transfer

Wenke Li, Beiqi Sun, Lei Zhang, Fanyang Mo

2023Green Chemistry41 citationsDOI

Abstract

We have pioneered a methodology for the visible-light-driven carboxylation of remote C−H bonds, employing a nitrogen-centered 1,5-hydrogen atom transfer (1,5-HAT) mechanism, with CO 2 serving as the carbon source.

Topics & Concepts

Hydrogen atomChemistryHydrogen bondCarboxylationPhotochemistryNitrogenNitrogen atomAtom (system on chip)Carbon fibersHydrogenMoleculeMaterials scienceCatalysisOrganic chemistryGroup (periodic table)Composite numberComputer scienceEmbedded systemComposite materialCarbon dioxide utilization in catalysisRadical Photochemical ReactionsCO2 Reduction Techniques and Catalysts